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Property Diagrams - Thermodynamics

The phases of a substance and the relationships between its properties are most commonly shown on property diagrams. A large number of different properties have been defined, and there aresome dependencies between properties. For example, at standard atmospheric pressure andtemperature above 212°F, water exists as steam and not a liquid; it exists as a liquid attemperatures between 32°F and 212°F; and, it exists as ice at temperatures below 32°F. Inaddition, the properties of ice, water, and steam are related. Saturated steam at 212°F andstandard atmospheric pressure has a specific volume of 26.8 ft3/lbm. At any other temperatureand pressure, saturated steam has a different specific volume. For example, at 544°F and 1000psia pressure, its specific volume is 0.488 ft3/lbm.

There are five basic properties of a substance that are usually shown on property diagrams.

These are: pressure (P), temperature (T), specific volume (n), specific enthalpy (h), and specificentropy (s). When a mixture of two phases, such as water and steam, is involved, a sixthproperty, quality (x), is also used.

There are six different types of commonly encountered property diagrams. 

These are: Pressure-Temperature (P-T) diagrams, Pressure-Specific Volume (P-n) diagrams, Pressure-Enthalpy (P-h)diagrams, Enthalpy-Temperature (h-T) diagrams, Temperature-entropy (T-s) diagrams, andEnthalpy-Entropy (h-s) or Mollier diagrams.

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