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Irreversible Process Thermodynamics

An irreversible process is a process that cannot return both the system and the surroundings to their original conditions. That is, the system and the surroundings would not return to their original conditions if the process was reversed. For example, an automobile engine does not give back the fuel it took to drive up a hill as it coasts back down the hill. There are many factors that make a process irreversible. Four of the most common causes of irreversibility are friction, unrestrained expansion of a fluid, heat transfer through a finite temperature difference, and mixing of two different substances. These factors are present in real,irreversible processes and prevent these processes from being reversible.

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